Cyclic voltammetry cv cyclic voltammetry is a method for investigating the electrochemical behaviour of a system. The polyaniline nanofibers with different sizes were synthesized by using cyclic voltammetry at different potential scan rates, in the presence of ferrocenesulfonic acid. Birss,z department of chemistry, university of calgary, calgary, alberta canada t2n 1n4 the electrochemical properties of polyaniline pani films, grown using multicycling methods, but using two different upper lim. All polymers described in this paper are very stable in air. A new electrochemically prepared composite counter. In cyclic voltammetry, the electrode potential ramps linearly versus time in cyclical phases figure 2. Panigraphene composites of different compositions were prepared by in situ polymerization of aniline to polyaniline in the presence of graphene. The electrochemical performance of the pani film is carried out by cyclic voltammetry in 1 m h2so4 solution.
Morphology and cyclic voltammetry analysis of in situ polymerized. Request pdf study of electropolymerised polyaniline films using cyclic voltammetry, atomic force microscopy and optical spectroscopy electropolymerisation of polyaniline pani has been. Apr 19, 2018 cyclic voltammetry cv was carried out in a potential range of. A polyvinyl alcoholpolyaniline based electroconductive. Cyclic voltammetry cyclic voltammetry of ferrocene carboxylic acid 1. Study of electropolymerised polyaniline films using cyclic. Electrically conductive composite of polyanilinearamid and. Cyclic voltammetry and its applications intechopen. With no use of manual brushing and nafion solution, the electrochemical synthesis of pani by. Electrochemical polymerization of anilinium hydrochloride arxiv. This demonstrates that the electropolymerized pani films can be served as a good candidate for ecd applications, taking advantage of their excellent properties in terms of chemical stability. Electrochemical characterization in nonaqueous electrolyte of polyaniline electrochemically prepared from aqueous media. Pdf determination of extremely low percolation threshold. Previously polyaniline films were obtained at the surface of au, pt, and cp electrodes 5153.
Its uses cover characterization, synthesis, mechanisms, and analysis. Cyclic voltammetry suggested that, the oxidationreduction current increased with an increase in scan rate and that the undoped polyaniline films were not. Keywords polyaniline, thin films, uvvis absorption, electrochromic property 1. Homogeneous and uniform coatings of polyaniline were successfully deposited on carbon fibers by an aqueous electrodeposition technique using ptoluene sulfonic acid as the electrolyte. A comparison of the experimental data obtained with the pt and panipt electrodes suggested that the reactions were catalyzed by the pani. Oriented polyaniline nanowire arrays grown on dendrimer. The results of cyclic voltammetry and battery test on the composite electrode revealed that the electrochemical activities of the composite are almost the same as those of the polyaniline single film. Chapteri introduction and overview of cyclic voltammetry and. Cyclic voltammogram recorded for polyaniline doped with hcl on a platinum working electrode using a scan rate of 0.
Cyclic voltammetry and conductivity investigations of polyaniline. Cyclic voltammetry and conductivity investigations of. Electrochemical synthesis and characterization of chloride doped. Electrocatalytic oxidation of methanol on glassy carbon. Characterization of electrochromic properties of polyaniline. The morphology of the pani nanotubes was determined by sem and tem and the electrical conductivity was. Sce in the presence and absence of aniline in the acqueous solution of hbf 4. Polyaniline pani, tungsten trioxide wo 3, and their composite are deposited on indium thin oxide substrates using cyclic voltammetry technique and employed as counter electrodes that reached comparable and superior performances than pt counter electrodes. Synthesis and characterization of polypyrrole by cyclic. The percolation threshold of prepared blends of polyvinyl chloride pvc with doped polyaniline pani from camphorsulfonic acid csa was investigated by cyclic. Electrochemical preparation of polyaniline supported cucuo. The pani thin film was deposited on the itoglass by cyclic voltammetry in 1 m ani and 2 m hcl with deionized d.
The electrochemical deposition of polyaniline nanofibers and nanoparticles have been investigated on gold electrodes by cyclic voltammetry and their morphology by high resolution scanning electron. Characterization of polyaniline pani by electrochemical and spectroscopic techniques are presented. Galvanostatic chargedischarge properties were measured in a. The peak which appears frequently in the middle of cyclic voltammetric curves of polyaniline is attributed to the presence of a polymer containing phenazine rings. Characterization of polyaniline by cyclic voltammetry and uv. Background cyclic voltammetry is a powerful analytical technique that provides information about the. Onoff switchable drug release was obtained by periodically applyingremovingreapplying an electric potential ranging from 0. Effect of substrate on polyaniline film properties. Electrodeposition and characterization of polyaniline on stainless steel surface via cyclic, convolutive voltammetry and sem in aqueous. Capacitance fading induced by degradation of polyaniline. Beatrice garcia, florence fusalba, and, daniel belanger. Cyclic voltammetry was employed for electroactivity and conductivity analysis.
Mar 27, 2014 abstract polyaniline was successfully synthesised using cyclic voltammetry. The rate of voltage change over time during each of these phases is known as the experiments scan rate vs. Detection of acetaminophen using cyclic voltammetry on mnfe 2 o 4 polyaniline hsiang. Electropolymerisation of polyaniline pani has been investigated using cyclic voltammetry in aqueous bath. Electrochemical characterization in nonaqueous electrolyte of. Determination of lead in waste water using cyclic voltammetry. Detection of acetaminophen using cyclic voltammetry on.
The polymer films have been studied by cyclic voltammetry. In this paper, we propose new counter electrodes for applications in dyesensitized solar cells dsscs. The deposited times were controlled for 10, 20, 30, 40, 50 and 60 times, respectively. In the present paper, we report electropolymerization from an electrolyte containing anilinium hydrochloride monomer in an acidified medium. Synthesis and properties of polyaniline slideshare. It is shown that variation in the conditions of aniline. In present work, the capacitance fading of pani nanofibers modified stainless steel paniss electrode was investigated by combination of cyclic voltammetry cv and scanning electron microscopy sem. Cyclic voltammetry cv is an electrochemical technique which measures the current that develops in an electrochemical cell under conditions where voltage is in excess of that predicted by the nernst equation.
In all applications, the technique can work well with a large variety of compounds including organic, inorganic. Polyaniline pani, an electrically conducting polymer, exhibits three redox states in. This peak appears during the polymerization of aniline at high potential and by oxidation of the polymer also, at a higher potential than the second voltammetric peak. Synthesis, characterization, and electrochemical properties. Results and discussion peak iii in the cyclic voltammetry of polyaniline appears in any kind of medium in which the polymer is prepared or cycled. The electrochemical investigation reveals the influence of the dopant acid on the kinetic parameters of polyaniline films. It was first reported in 1938 and described theoretically by randies 18. Aims to use cyclic voltammetry to investigate the solution electrochemistry of a simple redox couple. Cyclic voltammetry is a versatile method for scientific investigation and innovation due to the fact that most processes involve electron transfer, which makes them be able to be monitored by this technique. Cyclic voltammetry and impedance spectroscopy were used to characterize the resulting films deposited on a platinum electrode. Uvvis spectra of thin films of polyaniline in nmetil pyrrolidine solutions indicate the. A comparative study of the electrocatalytic oxidation of methanol is made in naoh, on ni and cu on polyaniline film covered glassy carbon electrode nipanigc, cupanigc at 25 catalytic activity for the oxidation of methanol was studied by using cyclic voltammetry. Characterization of polyaniline by cyclic voltammetry and.
These scenarios included the study in different acid. Electrochemical deposition of aniline was carried out by cyclic voltammetry in the potential range of. Using cyclic voltammetry cv, uniform layers of polyaniline are deposited on carbon electrode, as confirmed by scanning electron microscope observation. Spectral characteristics of polyaniline nanostructures. The cyclic voltammetry method was performed in a three electrodes system using platinum wire as a working electrode, an agagcl saturated kcl as reference electrode and platinum plate as the counter electrode.
Read cyclic voltammetry and conductivity investigations of polyaniline, journal of applied polymer science on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. The investigation of the electrochromic characteristics for. Spectral characteristics of polyaniline nanostructures synthesized by using cyclic voltammetry at different scan rates article in the journal of physical chemistry b 11237. Synthesis and characterization of polypyrrole by cyclic voltammetry at different scan rate and its use in electrochemical reduction of the simulant of nerve agents. Polyaniline pani, one of the most studied conducting polymers cps, shows great promising application in supercapacitor in advanced power system. Potentiodynamic synthesis of polyaniline the parameters of using cyclic voltammetry for 10 ml of the stock polyaniline solution were. Determination of lead in waste water using cyclic voltammetry by platinum wire electrode has been carried out. Cv is performed by cycling the potential of a working electrode, and measuring the resulting current. The cyclic voltammograms of polyaniline prepared electrochemically were examined in the range. Electrochemical polymerization of anilinium hydrochloride. Voltammetric potentials of polyaniline varying with electric. Pdf electrodeposition and characterization of polyaniline on. Selfassembled polyaniline pani nanotubes were prepared in the presence of three different sulfonic acids as dopant, namely, ptoluenesulfonic acid, camphorsulfonic acid, and tetrakis4sulfonatophenylporphyrin, by oxidative polymerization using ammonium peroxydisulfate as the oxidant.
Electrical conductivity studies of polyaniline nanotubes. Cyclic voltammetry and conductivity studies of polyaniline. Impedance and voltammetric studies of electrogenerated. Preparation and characterization of polyanilinezno composite. The cyclic voltammograms of polyaniline films prepared electrochemically in the aqueous solution of sulfosalicylic acid, naphthalene 2 sulfonic acid, anthraquinone2 sulfonic acid and polyacrylic acid were examined in the range of 0. The redox properties of emeraldine base, a polyaniline derivative, were explored, and it was proved using uvvis spectroscopy that emeraldine salt exists in a coiled form when using dmf as a solvent, but in the extended chain form in m cresol. In this work, electropolymerization at the surface of gc using consecutive cyclic voltammetry for 15 cycles between. In the first step, polyaniline pani film was electrodeposited on the 316l substrate from a solution of 0. Degradation hydrolysis can be observed in aqueous media only upon application of potentials greater than 0.
Effect of substrate on polyaniline film properties a cyclic voltammetry and impedance study huyen n. Os by thermal fluctuation and conversion rates of cyclic voltammetry. Cyclic voltammetry is the most widely used technique for acquiring qualitative information about electrochemical reactions. The potential scan rate controlled the formation and growth of polyaniline nuclei, which plays a key role in controlling nanofiber sizes. Potassium ion selective electrode using polyaniline and. The peak which appears frequently in the middle of cyclic voltammetric curves of polyaniline is attributed to the presence of a polymer containing phenazine. The morphology properties of span and mcn were characterized by transmission electron microscopy tem, and the electrochemical properties of the fabricated electrode were characterized by cyclic voltammetry cv.